Most of the Fluorine-Containing Phenylamine products are a light yellow oily liquid, relatively high density, insoluble in water. Most of them are used in the manufacturing of pesticides and dye intermediates, small part of them can be used as an analytical reagent. The steam or smoke of fluorine-containing phenylamine series is irritated to eyes, mucous membranes and upper respiratory. Vapor and air can form explosive mixtures, in case of fire, high-heat combustion caused the explosion. And oxidant may react. Decomposition by high fever and emit toxic gases. In case of high fever, increased pressure within containers, cracking and the risk of explosion. Protective measures must be done carefully during product storage. Once the fire occurred, it must be immediately evacuated from air leakage,personnel to a safe area, prohibit access to the contaminated area. Recommended emergency personnel wearing self-contained breathing apparatus and wear chemical protective clothing. In the ambulance personnel to ensure proper safety measures, immediately use foam, carbon dioxide, dry, sandy soil to put out a fire.